Faculté des sciences

Di-μ-diphenylphosphido-bis{chlorido[(mesitylmethyl)diphenylphosphine-κP]palladium(II)}

Chahen, Ludovic ; Therrien, Bruno ; Süss-Fink, Georg

In: Acta Crystallographica Section E, 2007, vol. 63, no. 7, p. m1989

In the title dinuclear palladium complex, [Pd2 (C12H10P)2Cl2 (C22H23P)2], the terminal ligands adopt a trans configuration with a Pd•••Pd distance of 3.6111 (4) Å. A crystallographic twofold rotation axis runs perpendicular to the Pd2P2 ring. The Cl atom lies slightly out of the... Plus

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    Summary
    In the title dinuclear palladium complex, [Pd2 (C12H10P)2Cl2 (C22H23P)2], the terminal ligands adopt a trans configuration with a Pd•••Pd distance of 3.6111 (4) Å. A crystallographic twofold rotation axis runs perpendicular to the Pd2P2 ring. The Cl atom lies slightly out of the plane of the Pd and three P atoms in each half of the molecule.