Faculté des sciences

(±)-Di-μ-chlorido-(μ-N,N'-{[3,3'-methylenebis(2,4,6-trimethyl-3,1-phenylene)]dimethylene}bis(2-methylpropan-2-amine))bis[chloridopalladium(II)]

Chahen, Ludovic ; Therrien, Bruno ; Süss-Fink, Georg

In: Acta Crystallographica Section E, 2007, vol. 63, no. 11, p. m2687

In the title dinuclear palladium complex, [Pd2Cl4 (C29H46N2)], the terminal ligands adopt an anti configuration, with an intramolecular metal-metal distance of 3.3625 (5) Å. The dinuclear palladium complex adopts a V-shaped conformation, with a dihedral angle of 152.67 (3)° between the two chloride-bridged PdNCl3 square-planar... Plus

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    Summary
    In the title dinuclear palladium complex, [Pd2Cl4 (C29H46N2)], the terminal ligands adopt an anti configuration, with an intramolecular metal-metal distance of 3.3625 (5) Å. The dinuclear palladium complex adopts a V-shaped conformation, with a dihedral angle of 152.67 (3)° between the two chloride-bridged PdNCl3 square-planar systems. The benzene rings in the chelating amine ligand are at an angle of 74.9 (1)° with respect to each other. The complex is the first example of chloride-bridged dinuclear palladium complex with a bidentate secondary amine ligand.