Faculté des sciences

Di-μ-chloro-bis[(η6-benzene)chlororuthenium(II)] chloroform disolvate

Canivet, Jérôme ; Therrien, Bruno ; Süss-Fink, Georg

In: Acta Crystallographica Section E, 2005, vol. 61, no. 6, p. m1090-m1091

In the centrosymmetric dinuclear title complex, [RuCl2 (η6-C6H6)]2•2CHCl3 or [Ru2Cl4(C6H6)2]•2CHCl3, accessible from RuCl3.nH2O and 1,3-cyclohexadiene, the benzene ligands are involved in slipped-parallel -... Plus

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    Summary
    In the centrosymmetric dinuclear title complex, [RuCl26-C6H6)]22CHCl3 or [Ru2Cl4(C6H6)2]•2CHCl3, accessible from RuCl3.nH2O and 1,3-cyclohexadiene, the benzene ligands are involved in slipped-parallel - stacking interactions with neighbouring molecules, thus forming one-dimensional polymeric chains.