Faculté des sciences

Di-μ-pivalamidato-bis[dicarbonyl(triphenylphosphine)ruthenium(II)](Ru-Ru)

Auzias, Mathieu ; Therrien, Bruno ; Süss-Fink, Georg

In: Acta Crystallographica Section E, 2005, vol. 61, no. 11, p. 2426-2427

The title dinuclear ruthenium complex, [Ru2 (C5H19NO)2 (C18H15P)2 (CO)4], has been synthesized from Ru3 (CO)12, pivalamide and triphenylphosphine. The structure shows a Ru2 (CO)4 sawhorse backbone with the two OCNH bridges being transoid with respect to each other. Plus

Ajouter à la liste personnelle
    Summary
    The title dinuclear ruthenium complex, [Ru2 (C5H19NO)2 (C18H15P)2 (CO)4], has been synthesized from Ru3 (CO)12, pivalamide and triphenylphosphine. The structure shows a Ru2 (CO)4 sawhorse backbone with the two OCNH bridges being transoid with respect to each other.