Faculté des sciences

Half-sandwich trihydrido ruthenium complexes

Osipov, Alexandr L. ; Gutsulyak, Dmitry V. ; Kuzmina, Lyudmila G. ; Howard, Judith A.K. ; Lemenovskii, Dmitry A. ; Süss-Fink, Georg ; Nikonov, Georgii I.

In: Journal of Organometallic Chemistry, 2007, vol. 692, no. 22, p. 5081-5085

This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R3P)Ru(NCCH3)2][PF6] with LiAlH4. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of... Plus

Ajouter à la liste personnelle
    Summary
    This paper reports facile preparation of half-sandwich trihydrido complexes of ruthenium based on the reactions of the readily available precursors [Cp(R3P)Ru(NCCH3)2][PF6] with LiAlH4. The target complexes were characterized by spectroscopic methods and X-ray structure analysis of Cp(PhPri2P)RuH3.